KOCH REFINING CO. -- GASOLINE,UNLEADED  -- 9130-00-148-7103
<pre>=====================  Product Identification  =====================

Product ID:GASOLINE,UNLEADED
MSDS Date:03/01/1988
FSC:9130
NIIN:00-148-7103
=== Responsible Party ===
Company Name:KOCH REFINING CO.
Address:SUNTIDE RD
Box:2608
City:CORPUS CHRISTI
State:TX
ZIP:78403
Country:US
Emergency Phone Num:NONE
Preparer's Name:DALE F. JANES
CAGE:3V260
=== Contractor Identification ===
Company Name:KOCH REFINING CO INC
Address:SUNTIDE RD
Box:2608
City:CORPUS CHRISTI
State:TX
ZIP:78403
Country:US
Phone:512-241-4811
CAGE:3V260

=============  Composition/Information on Ingredients  =============

Ingred Name:GASOLINE
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9192

Ingred Name:BENZENE  (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 1.5%
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:PARAFFINS
Fraction by Wt: 46%
Other REC Limits:100 PPM

Ingred Name:OLEFINS
Fraction by Wt: 17%
Other REC Limits:100 PPM

Ingred Name:NAPHTHENES
Fraction by Wt: 8%
Other REC Limits:100 PPM

Ingred Name:OTHER AEROMATIC HYDROCARBONS
Fraction by Wt: 27%
Other REC Limits:100 PPM

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO
    EYES,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS
    SYSTEM. CHRONIC OVER EXPOSURE MAY CAUSE LIVER,KIDNEY, OR CENTRAL
    NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE.
    ALSO,AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE
    VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION.
    INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION
    INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWINESS,FATIGUE,TREMORS,CON
    VULSION,NAUSEA,VOMITING,DIAR RHEA,LOSS OF CONSCIOUSNESS. AND
    FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO
    THOSE UNDER "INHALED".
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN CONDITIONS OR
    IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT.

=======================  First Aid Measures  =======================

First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
    REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED:REMOVE
    TO FRESH AIR .RESUSCITATE OR GIVE OXYGEN AS NEEDED.GET MEDICAL
    ATTENTION. DO  NOT INDUCE VOMITING. IF VOMITING OCCURS,MINIMIZE
    ASPIRATION HAZARD.

=====================  Fire Fighting Measures  =====================

Flash Point:-40F
Autoignition Temp:Autoignition Temp Text:>536F
Lower Limits:1.3
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER
    MAY BE INEFFECTIVE,AS PRODUCT WILL FLOAT AND MAY SPREAD FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED  BREATHING APPARATUS IN
    CLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED
    CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING
    IN LOW AREAS,TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT
    IGNITION SOURCE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE
    PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.
    DIKE AS NEEDED TO KEEP SPILL FROM DRAINS, WATERS ETC. WATER FOG MAY
    BE USED TO REDUCE VAPO RS & PERSONAL HAZARD. REPORT SPILL PER LAW.
Neutralizing Agent:NONE

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATE,WELL
    VENTILATED AREA. KEEP IGNITION SOURCES AWAY. GROUND CONTAINERS TO
    PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSIION ARE THE ACUTE HSAZARDS OF THIS
    +PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF NEEDED,USE NIOSH/MSHA RESPIRATOR WITH ORGANIC
    VAPOR CARTRIDGE OR PREFERRABLY,APOSITIVE PRESSURE AIR SUPPLIED
    RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
    EXPOSURE BELOW PEL/TVL
Protective Gloves:IMPERVIOUS RUBBER OR POLYMER.
Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS
    NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
    UNNECESSARY CONTACT. MINIMIZE ALL CONTACT.
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

HCC:F1
Boiling Pt:=29.4C, 85.F
Vapor Density:3.5 (AIR)
Spec Gravity:0.72 - 0.76
Solubility in Water:NEGLIGIBILE
Appearance and Odor:CLEAR,COLORLESS TO STRAW YELLOW LIQUID;GASOLINE
    ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION
    SOURCES,VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
    PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF
    RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE ACCEPTABE
    DISPOSAL METHOD.

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